A halogen bond route to shorten the ultrashort sextuple bonds in Cr-2 and Mo-2

作者:Joy Jyothish; Jemmis Eluvathingal D
来源:Chemical Communications, 2017, 53(58): 8168-8171.
DOI:10.1039/c7cc04653g

摘要

Selective extraction of destabilizing σ-electrons from the sextuple bond of Cr2 and Mo2via σ-hole on a halogen bond donor shortens and strengthens the ultra-short metal–metal bond.

  • 出版日期2017-7-25
  • 单位Indian Institute of Science Education and Research