A versatile route to homo- and hetero-bimetallic 5f-5f and 3d-5f complexes supported by a redox active ligand framework

作者:Camp Clement; Toniolo Davide; Andrez Julie; Pecaut Jacques; Mazzanti Marinella*
来源:Dalton Transactions, 2017, 46(34): 11145-11148.
DOI:10.1039/c7dt01993a

摘要

The salt-elimination reaction of the complex [Na2U(bis-salophen)] with metal halides provides an entry to the synthesis of well-defined homobimetallic uranium-uranium and rare heterobimetallic uranium-cobalt and uranium-nickel complexes supported by a redox-active dinucleating ligand.

  • 出版日期2017-9-14