A novel method for analysis and prediction of methanol mass transfer in direct methanol fuel cell

作者：Ji, Feng; Yang, Linlin^*; Sun, Hai; Wang, Suli; Li, Huanqiao; Jiang, Luhua; Sun, Gongquan^*

来源：Energy Conversion and Management, 2017, 154: 482-490.

DOI：10.1016/j.enconman.2017.10.083

• Gas/liquid flow coupled with electrochemical reaction
• Direct methanol fuel cell
• Mass transfer coefficient
• Fuel utilization efficiency
• Dimensional analysis

Two-phase gas/liquid flows coupled with electrochemical reactions in the anode of direct methanol fuel cell (DMFC) are quite complicated transport phenomena. The methanol transport is a key factor influencing the performance as well as fuel utilization efficiency. In this paper, a dimensionless correlation of methanol mass transfer in DMFC anode is proposed. Firstly, a method for detecting methanol concentration in catalyst layer was developed, which is the key parameter to obtain the mass transfer coeffidient. Then, the influences of the various factors on the mass transfer coefficient, including physical properties of fluid, structures of the electrode, cell configuration and cell operation conditions, were investigated. And a correlation between four dimensionless groups, i.e., Sh, Re, Sc and II (ratio of consumption and feeding rate of methanol), was deduced using the dimensional analysis. Finally, MEA optimization and fuel utilization efficiency evaluation based on the above analysis is performed. A maximum power density of 178 mW cm(-2) at 80 degrees C and atomistic air is achieved, 40% higher than that of commercial one made by Johnson Matthery.

• 出版日期2017-12-15
• 单位中国科学院大连化学物理研究所; 中国科学院大学