Macrocyclic regioregular poly(3-hexylthiophene): from controlled synthesis to nanotubular assemblies

作者:Coulembier Olivier*; Deshayes Gaelle; Surin Mathieu; De Winter Julien; Boon Florian; Delcourt Cecile; Leclere Philippe; Lazzaroni Roberto; Gerbaux Pascal; Dubois Philippe
来源:Polymer Chemistry, 2013, 4(2): 237-241.
DOI:10.1039/c2py20647a

摘要

An easy and quantitative cyclization procedure based on an intramolecular imperfect aldol reaction from a pre-generated regioregular poly(3-hexylthiophene) is developed. As an illustration of the versatility of this procedure, the synthesis of a representative macrocyclic poly(3-hexylthiophene) with a diameter of 5 nm is presented.

  • 出版日期2013