Highly efficient and expeditious PdO/SBA-15 catalysts for allylic oxidation of cyclohexene to cyclohexenone

作者：Ganji Saidulu^*; Bukya Padma; Vakati Venkateswarlu; Rao Kamaraju Seetha Rama; Burri David Raju

来源：Catalysis Science & Technology, 2013, 3(2): 409-414.

DOI：10.1039/c2cy20627g

A series of four PdO/SBA-15 catalysts with 1, 2, 4, 5% (by weight) loading of PdO have been prepared by a conventional impregnation method and are characterized by N-2-adsorption, low-angle and wide-angle XRD, XPS and TEM techniques. The catalysts exhibited very high conversion of cyclohexene and high selectivity of cyclohexenone with 70% t-BuOOH in CH3CN. The structural and textural characteristics of catalysts play a crucial role in high conversion and selectivity.

• 出版日期2013