Ultrafast Studies of Exciton Migration and Polaron Formation in Sequentially Solution-Processed Conjugated Polymer/Fullerene Quasi-Bilayer Photovoltaics

作者：Ayzner Alexander L; Doan Stephanie C; de Villers Bertrand Tremolet; Schwartz Benjamin J^*

来源：Journal of Physical Chemistry Letters, 2012, 3(16): 2281-2287.

DOI：10.1021/jz300762c

We examine the ultrafast dynamics of exciton Migration and polaron production in sequentially. processed 'quasi-bilayer' and preblended 'bulk heterojunction' (BHJ) solar cells based on conjugated polymer films that contain the same total amount of fullerene. We find that even though the polaron yields are similar, the dynamics of polaron production are significantly slower in quasi-bilayers than BHJs. We argue that the different polaron production dynamics result from the fact that (1) there is significantly less fullerene inside the polymer in quasi-bilayers than in BHJs and (2) sequential processing yields polymer layers that are significantly more ordered than BHJs. We also argue that thermal annealing improves the performance of quasi-bilayer solar cells not because annealing drives additional fullerene into the polymer but because annealing improves the fullerene crystallinity. All of the results suggest that sequential processing remains a viable alternative for producing polymer/fullerene solar cells with a nanometer-scale architecture that differs from BHJs.

• 出版日期2012-8-16