科研之友
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摘要
Sonochemical switching%26apos; whereby the pathway of a reaction is changed under sonication conditions was first reported by Ando, and in fact could just be the consequence of efficient agitation. We herein report a new addition to this switching phenomenon in which epoxides are converted to cyclic carbonates by addition of CO2 under standard heating/electrolysis conditions but are switched%26apos; to alkenes under deoxygenating sonochemical conditions.
- 出版日期2014-1-23
