Non-blinking quantum dot with a plasmonic nanoshell resonator

作者：Ji Botao; Giovanelli Emerson; Habert Benjamin; Spinicelli Piernicola; Nasilowski Michel; Xu Xiangzhen; Lequeux Nicolas; Hugonin Jean Paul; Marquier Francois; Greffet Jean Jacques^*; Dubertret Benoit

来源：Nature Nanotechnology, 2015, 10(2): 170-175.

DOI：10.1038/NNANO.2014.298

Colloidal semiconductor quantum dots are fluorescent nanocrystals exhibiting exceptional optical properties, but their emission intensity strongly depends on their charging state and local environment. This leads to blinking at the singleparticle level or even complete fluorescence quenching, and limits the applications of quantum dots as fluorescent particles. Here, we show that a single quantum dot encapsulated in a silica shell coated with a continuous gold nanoshell provides a system with a stable and Poissonian emission at room temperature that is preserved regardless of drastic changes in the local environment. This novel hybrid quantum dot/silica/gold structure behaves as a plasmonic resonator with a strong Purcell factor, in very good agreement with simulations. The gold nanoshell also acts as a shield that protects the quantum dot fluorescence and enhances its resistance to high-power photoexcitation or high-energy electron beams. This plasmonic fluorescent resonator opens the way to a new family of plasmonic nanoemitters with robust optical properties.

• 出版日期2015-2