Alteration of the unsteady sorption behaviour of maple (Acer pseudoplatanus L.) and spruce (Picea abies (L.) Karst.) due to thermal modification

作者：Pfriem Alexander^*; Zauer Mario; Wagenfuehr Andre

来源：Holzforschung, 2010, 64(2): 235-241.

DOI：10.1515/HF.2010.029

• diffusion coefficient
• Fick's second law
• non-Fickian moisture transfer
• pore structure
• sorptions direction
• thermal modification
• unsteady sorption

The aim of the present investigation was to evaluate the influence of a thermal modification on the kinetics of the water vapour sorption of maple (Acer pseudoplatanus L.) and spruce [Picea abies (L.) Karst. x based on the assumption that the Fickian equation can be applied in this regard in the first approximation. The unsteady-state sorption process between two equilibria of humidity was modelled as a diffusion process. The rate of sorption was recorded by the gravimetric method, and then the diffusion coefficient was determined through inverse parameter identification. The thermal modification leads to an alteration of the unsteady sorption behaviour of both wood species. Transport of water vapour decreases with increasing degree of modification. Depending on wood moisture, the trends of diffusion coefficients include all three levels of modification. Furthermore, the diffusion coefficients decrease when the thickness of specimens decreases. The calculated diffusion coefficients showed a length dependency both for unmodified and thermally modified spruce and maple. Accordingly, the results clearly show that these woods have a non-Fickian moisture transport behaviour. The results are nevertheless useful for comparative purposes.

• 出版日期2010-2