Nickel-catalyzed directed sulfenylation of sp(2) and sp(3) C-H bonds

作者:Ye Xiaohan; Petersen Jeffrey L; Shi Xiaodong
来源:Chemical communications, 2015, 51(37): 7863-7866.
DOI:10.1039/c5cc01970b

摘要

Directed sulfenylation of both sp(2) and sp(3) C-H bonds was achieved through nickel catalyzed directed C-S bond formation, giving the desired product in good to excellent yield (up to 90%). Other metal cations, including Cu, Fe, Pd, Rh, Ru and Co, gave almost no reaction under identical conditions, which highlighted the unique reactivity of this Ni system.

  • 出版日期2015