Aromatization of Isobutene Using H-ZSM-5/Oxide Composite Catalysts

作者:Al Otaibi Naif M; Hutchings Graham*
来源:Catalysis Letters, 2010, 134(3-4): 191-195.
DOI:10.1007/s10562-009-0255-x

摘要

Aromatization of isobutene was investigated using zeolite H-ZSM-5 (Si/Al = 30) as well as physical mixtures of H-ZSM-5 with metal oxides (Ga(2)O(3), ZnO and CuO). The study was aimed at determining the effect on the selectivity to aromatic products by introducing an oxide/zeolite interface. Of the three oxides, ZnO was found to enhance the yield of aromatic products with the highest aromatic selectivity being attained with ZnO/H-ZSM-5 (1: 2 weight ratio). The addition of Ga(2)O(3) had very little effect and the addition of CuO was not found to be beneficial.

  • 出版日期2010-2