科研之友
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摘要
Torrefaction is a thermo-chemical conversion process improving the handling, storage and combustion properties of wood. To save storage space and transportation costs, it can be compressed into fuel pellets of high physical and energetic density. The resulting pellets are relatively resistant to moisture uptake, microbiological decay and easy to comminute into small particles. The present study focused on the pelletizing properties of spruce torrefied at 250, 275 and 300 degrees C. The changes in composition were characterized by infrared spectroscopy and chemical analysis. The pelletizing properties were determined using a single pellet press and pellet stability was determined by compression testing. The bonding mechanism in the pellets was studied by fracture surface analysis using scanning electron microscopy. The composition of the wood changed drastically under torrefaction, with hemicelluloses being most sensitive to thermal degradation. The chemical changes had a negative impact, both on the pelletizing process and the pellet properties. Torrefaction resulted in higher friction in the press channel of the pellet press and low compression strength of the pellets. Fracture surface analysis revealed a cohesive failure mechanism due to strong inter-particle bonding in spruce pellets as a resulting from a plastic flow of the amorphous wood polymers, forming solid polymer bridges between adjacent particles. Fracture surfaces of pellets made from torrefied spruce possessed gaps and voids between adjacent particles due to a spring back effect after pelletization. They showed no signs of inter-particle polymer bridges indicating that bonding is likely limited to Van der Waals forces and mechanical fiber interlocking.
- 出版日期2011-11
