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摘要
An %26apos;arene exchange%26apos; approach has been successfully applied for the first time to the synthesis of Ru(II)-based %26apos;tethered%26apos; reduction catalysts directly from their ligands in one step. This provides an alternative method for the formation of known complexes, and a route to a series of novel complexes. The novel complexes are highly active in both asymmetric transfer and pressure hydrogenation of ketones.
- 出版日期2013-10-4
