Bird-like spiro-metallacyclic complexes based on a bent oxadiazole bridging ligand

作者:Zhao Xia Xia; Ma Jian Ping; Shen Da Zhong; Dong Yu Bin*; Huang Ru Qi
来源:CrystEngComm, 2009, 11(7): 1281-1290.
DOI:10.1039/b818753n

摘要

The coordination chemistry of a new symmetric organic ligand 2,5-bis(3-(1H-1,2,4-triazol-1-ylmethyl) phenyl)-1,3,4-oxadiazole (L2) with inorganic M(II) (M = Cd, Co, Cu and Mn) salts has been investigated. Eight new bird-like spiro-metallocyclic complexes (1-8) were synthesized. In addition, the luminescent properties of 1-8 and the electrical conductivity of 6 were investigated primarily.