A Novel, Layered Phase in Ti-Rich SrTiO3 Epitaxial Thin Films

作者:Lee Sungki; Damodaran Anoop R; Gorai Prashun; Oh Nuri; Moyer Jarrett A; Kwon Ji Hwan; Ferdous Naheed; Shah Amish; Chen Zuhuang; Breckenfeld Eric; Mangalam R V K; Braun Paul V; Schiffer Peter; Shim Moonsub; Zuo Jian Min; Ertekin Elif; Martin Lane W*
来源:Advanced Materials, 2015, 27(5): 861-868.
DOI:10.1002/adma.201403602

摘要

Sr2Ti7O14, a new phase, is synthesized by leveraging the innate chemical and thermodynamic instabilities in the SrTiO3-TiO2 system and non-equilibrium growth techniques. The chemical composition, epitaxial relationships, and orientation play roles in the formation of this novel layered phase, which, in turn, possesses unusual charge ordering, anti-ferromagnetic ordering, and low, glasslike thermal conductivity.

  • 出版日期2015-2-4