摘要

Landau expansion of free energy assuming dual instabilities for the nano-segregated SmA phase is analyzed. In addition to known phase sequences (on cooling, disordered isotropic liquid -> nematic phase -> smectic phase, and disordered isotropic liquid -> smectic phase), a new sequence (disordered isotropic liquid -> density wave with subsidiary nematic order -> smectic phase) and the existence of a critical point are demonstrated in the case where the instability for density wave formation occurs at a higher temperature.

  • 出版日期2015