Nickel(0)-Catalyzed N-Allylation of Amides and p-Toluenesulfonamide with Allylic Alcohols under Neat and Neutral Conditions

作者：Azizi Mohamed Salah; Edder Youssef; Karim Abdallah; Sauthier Mathieu^*

来源：European Journal of Organic Chemistry, 2016, 2016(22): 3796-3803.

DOI：10.1002/ejoc.201600500

• Homogeneous catalysis
• Nickel
• N-Allylation
• Allylic alcohols
• Amides
• Electron-poor N atoms

Nickel(0)-catalyzed direct N-allylation of amides and p-toluenesulfonamide with allylic alcohols took place in the presence of Ni-0-diphosphine complexes. The corresponding N-allylated (and/or N, N-diallylated) products were obtained in moderate to high yields under neutral conditions.

• 出版日期2016-8