Luminescence of Mn2+ ions in Tb3Al5O12 garnet

作者：Zorenko Yu^*; Gorbenko V; Voznyak T; Batentschuk M; Osvet A; Winnacker A

来源：Journal of Luminescence, 2010, 130(3): 380-386.

DOI：10.1016/j.jlumin.2009.09.024

• TbAG
• Luminescence
• Mn2+ and Ce3+ dopants
• Single crystalline films
• Energy transfer

The paper is dedicated to investigation of the Mn3+ luminescence in Tb3Al5O12 (TbAG) garnet, as well as the processes of excitation energy transfer between host cations (Tb3+ ions) and activators (Mn2+ and Mn2+-Ce3+ pair ions) in single crystalline films of ThAG:Mn and TbAG:Mn,Ce garnets which can be considered as promising luminescent materials for conversion of LED's radiation. Due to the effective energy transfer between TbAG host and activator, Mn2+ ions in TbAG possess the bright orange luminescence in the bands peaked at 595 nm with a lifetime of 0.64 ms which are caused by the T-4(1) -> (6)A(1) radiative transitions. The simultaneous process of energy transfer is realized in TbAG:Mn,Ce: (i) from Tb3+ to Mn2+ ions; (ii) from Tb3+ cations to Ce3+ ions and then partly to Mn2+ ions through Tb3+ ion sublattice and Ce-Mn dipole-dipole interaction.

• 出版日期2010-3