Mechanisms of C-H bond activation: rich synergy between computation and experiment

作者:Boutadla Youcef; Davies David L*; Macgregor Stuart A; Poblador Bahamonde Amalia I
来源:Dalton Transactions, 2009, (30): 5820-5831.
DOI:10.1039/b904967c

摘要

Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C-H bonds. The term 'ambiphilic metal ligand activation' (AMLA) is introduced to describe such reactions.

  • 出版日期2009