Determination of concentration and enantiomeric excess of amines and amino alcohols with a chiral nickel(II) complex

作者:He Xuan; Zhang Qi; Liu Xiaohua; Lin Lili; Feng Xiaoming*
来源:Chemical communications, 2011, 47(42): 11641-11643.
DOI:10.1039/c1cc14660b

摘要

A chiral N,N'-dioxide-Ni(II) complex was found to exhibit highly enantioselective fluorescent recognition of chiral amines and amino alcohols. It can be used to determine their concentration and ee value. Using a 96-well plate, high-throughput screening for enantiomer discrimination was accomplished.