A growing family: New structures of coordination polymers containing adamantane-shaped phosphorus-nitrogen cage ligands

作者：Spore Alex B; Rizzo Natalie M; Noll Bruce C; Sommer Roger D^*

来源：Inorganica Chimica Acta, 2010, 364(1): 261-265.

DOI：10.1016/j.ica.2010.08.052

• Coordination polymers
• Phosphorus-nitrogen
• Copper

Two new structurally characterized coordination polymers containing the P-4(NR)(6) ligand system are described. A convenient one-pot synthesis of P-4(NR)(6) (R = benzyl) via reaction of lithiated primary amine with phosphorus trichloride demonstrates an expanded scope for the preparation of this adamantane-type structure. Reactions of P-4(NR)(6) (R = Et, Bn) with cuprous iodide yield different products due to the differences in steric demands of the ligands.

• 出版日期2010-12-15