A 2D -> 3D net with coexistence of polycatenation and polythreading constructed by long rigid and flexible ligands

作者：Zhao Fang Hua; Che Yun Xia; Zheng Ji Min^*

来源：CrystEngComm, 2012, 14(20): 6397-6399.

DOI：10.1039/c2ce25911g

A new nickel complex, [Ni(pim)(bibp)(1.5)(H2O)]center dot 1.25H(2)O (1, pim = pimelic acid, bibp = 4,4'-bis(1-imidazolyl)biphenyl), was obtained via hydrothermal synthesis. The complex shows an unprecedented 2D -> 3D net with the coexistence of polycatenation and polythreading based on the T-shaped bilayer motifs.

• 出版日期2012
• 单位南开大学