科研之友
微信
新浪微博
Facebook
分享链接
摘要
The enol-keto transition rate constants in 2 %26apos;-methylacetophenone observed by Grellmann et al. [3] are calculated from first principles. The results reinterpret the proposed mechanism and show that proton tunneling is preceded by dissociation of a substrate-solvent complex rather than by rotamer interconversion.
- 出版日期2013-10-24
