Hydrogen Production in the Radiolysis of Dodecane and Hexane

作者:LaVerne Jay A*; Kleemola Sarah R
来源:Solvent Extraction and Ion Exchange, 2017, 35(3): 210-220.
DOI:10.1080/07366299.2017.1312887

摘要

The yields of molecular hydrogen, H-2, have been measured in the radiolysis of dodecane and hexane following radiolysis by.-rays and a variety of heavy ions. Measured yields with.-rays are found to be slightly higher than literature values and decrease by about 25% on aeration of the sample. Increasing the linear energy transfer (LET) from.-rays to radiolysis with protons results in a decrease of H-2 yields by about 15% due to the increased importance of second-order H atom combination reactions. A further increase in LET results in a slight increase in H-2 yields.

  • 出版日期2017