Hybrid Cyclic Water-Chloride Cluster Self-assembled in a Ruthenium(II) Polypyridyl Complex

作者：Bhat Satish S^*; Revankar Vidyanand K

来源：Journal of Chemical Crystallography, 2016, 46(1): 9-14.

DOI：10.1007/s10870-015-0621-z

• Ruthenium
• Polypyridyl
• Water-chloride cluster
• Crystal structure

A two-dimensional cyclic water-chloride anionic {[H2O)(18)(Cl)(8)](8-)}(n) network has been identified in a ruthenium(II) complex [Ru(bpy)(2)(tdzp)](2)center dot tdzp center dot Cl-4 center dot 9H(2)O (bpy = 2,2'-bipyridine, tdzp = [1,2,5]-thiadiazolo-[3,4-f]-[1,10]-phenanthroline). The compound crystallized in monoclinic space group P2(1)/c.
A two-dimensional cyclic water-chloride anionic {[H2O)(18)(Cl)(8)](8)-}n network has been identified in a ruthenium(II) complex [Ru(bpy)(2)(tdzp)](2)a <...tdzpa <...Cl(4)a <...9H(2)O (bpy=2,2'-bipyridine, tdzp=[1,2,5]-thiadiazolo-[3,4-f]-[1,10]-phenanthroline).
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• 出版日期2016-1