A fast bottom-up route for preparing CdS quantum dots using laser ablation in a liquid environment

作者：Mendonca Leonardo T B; de Azevedo Walter M^*

来源：Journal of Luminescence, 2016, 171: 79-84.

DOI：10.1016/j.jlumin.2015.10.031

• Laser ablation technique
• Cds quantum dots
• Thioglycerol as a catalyst

In this paper bright, water-dispersible and very stable CdS quantum dots (QDs) emitting from 400 to 700 nm with a narrow size distribution were synthesized in aqueous medium using a combination of the laser ablation technique and the action of thioglycerol as a catalyst for the hydrolysis of thiosulfate and as a stabilizing agent for the nanoparticles. In this case, instead of using a conventional, highly toxic sulfur source like H2S, the decomposition of thiosulfate catalyzed by thioglycerol is used to produce S2- ions that interact with Cd2+ ions produced by the ablation of a Cd foil by the second order light of a pulsed Nd:YAG laser. The ejected Cd2+ ions react with S2- to form CdS quantum dots. Spectroscopic, X-ray and TEM measurement analysis showed that 2.75 nm monodisperse CdS QDots were synthesized and exhibited bright photoluminescence in the yellow-orange region of the spectra when excited with 355 nm with a quantum yield of 3.25%.

• 出版日期2016-3