Adsorption of As(III) on chitosan-Fe-crosslinked complex (Ch-Fe)

作者：dos Santos Helen Helena; Demarchi Carla Albertina; Rodrigues Clovis Antonio^*; Greneche Jean Marc; Nedelko Nataliya; Slawska Waniewska Anna

来源：Chemosphere, 2011, 82(2): 278-283.

DOI：10.1016/j.chemosphere.2010.09.033

• Chitosan iron complex
• As(III)
• Adsorption isotherm
• Mossbauer spectroscopy

It was reported the adsorption of As(III) on the surface of the chitosan-Fe-crosslinked complex. Theoretical correlation of the experimental equilibrium adsorption data for As(III)/Ch-Fe system is best explained by the non-linearized form Langmuir-Freundlich isotherm model. At optimum conditions, pH 9.0, the maximum adsorption capacity, calculated using the Langmuir-Freundlich isotherm model was 13.4 mg g(-1). The adsorption kinetics of As(III) onto Ch-Fe are described by the pseudo-first-order kinetic equation. The results of the Mossbauer spectroscopy showed that there is no redox process on the surface of the adsorbent.

• 出版日期2011-1