Aqueous-Phase Deactivation and Intramolecular [2+2+2] Cycloaddition of Oxanorbornadiene Esters

作者：Kislukhin Alexander A; Higginson Cody J; Finn M G^*

来源：Organic Letters, 2011, 13(7): 1832-1835.

DOI：10.1021/ol103153f

Both inter- and intramolecular degradation pathways were identified for the aqueous phase deactivation of oxanorbornadiene (OND) electrophiles, and propargylic OND esters were found to undergo facile intramolecular [2 + 2 + 2] homo-Diels-Alder cycloaddition in polar media.

• 出版日期2011-4-1