An Efficient, Selective, and Reducing Agent-Free Copper Catalyst for the Atom-Transfer Radical Addition of Halo Compounds to Activated Olefins

作者：Maria Munoz Molina Jose; Belderrain Tomas R^*; Perez Pedro J

来源：Inorganic Chemistry, 2010, 49(2): 642-645.

DOI：10.1021/601942p

Efficient and selective ATRA reactions Of CCl(4), C r(4), TsCl (Ts = tosyl), or Cl(3)CC (2)Et with activated olefins (styrene, methyl methacrylate, n-butyl methacrylate, tert-butyl methacrylate) using the Tp(tBu)Cu(NCMe) complex as a catalyst have been achieved in the absence of any reductant and with low catalyst loadings.

• 出版日期2010-1-18