Composite Microstructure and Formation Mechanism of Calcium Phosphate Conversion Coating on Magnesium Alloy

作者：Su, Yingchao; Su, Yichang; Lu, Yanbo; Lian, Jianshe; Li, Guangyu^*

来源：Journal of the Electrochemical Society, 2016, 163(9): G138-G143.

DOI：10.1149/2.0801609jes

• SIMULATED BODY-FLUID
• ZINC PHOSPHATE
• IN-VITRO
• CORROSION BEHAVIOR
• MG-8.8LI ALLOY
• HYDROXYAPATITE
• AZ31
• BONE
• MG
• DEGRADATION

In order to improve the biodegradability and surface biocompatibility of magnesium (Mg) alloys, a calcium phosphate conversion coating (CPCC) was deposited onto an AZ60 Mg alloy. The coating's components and composite microstructure and its formation mechanism were studied using electrochemical measurements, scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy and by developing a thermodynamic stability diagram. The results revealed that the presence of Mg2+ originating from the electrochemical reaction of the Mg alloy could affect the precipitation of different coating components. Because the concentration of Mg2+ at the solution/coating interface continuously changed, three layers of the conversion coating were progressively produced. The inner layer was composed of magnesium hydrogen phosphate trihydrate (MHPT, MgHPO4 center dot 3H(2)O) and had a thickness of similar to 1.1 mu m. The middle layer was similar to 1.6 mu m thick and consisted of dicalcium phosphate dihydrate (DCPD, CaHPO4 center dot 2H(2)O), magnesium whitlockite (MWH, Ca9Mg(HPO4)(PO4)(6)), and MHPT. The top layer was similar to 2.3 mu m thick and was composed of a combination of DCPD and MWH.

• 出版日期2016
• 单位吉林大学