A series of red-light-emitting ionic iridium complexes: Structures, excited state properties, and application in electroluminescent devices

作者：Liu Shu Juan; Zhao Qiang; Fan Qu Li^*; Huang Wei

来源：European Journal of Inorganic Chemistry, 2008, (13): 2177-2185.

DOI：10.1002/ejic.200701184

• excited states
• iridium
• ionic complexes
• phosphorescence

A series of ionic diiminoiridium complexes [Ir(piq-C boolean AND N)(2)(L-N boolean AND N)](PF(6)) were prepared, where piq-C boolean AND N is 1-phenylisoquinolinato and L-N boolean AND N are bidentate N-coordinating ligands: 2,2';-bipyridine (bpy), 4,4';-dimethyl-2,2';-bipyridine (mbpym), 5,5';-bis(thiopen-2-yl)-2,2';-bipyridine (tbpyt), and 5,5';-bis(9,9-dioctylfluoren-2-yl)-2,2';-bipyridine (FbpyF). X-ray diffraction studies of [Ir(piq)(2)(mbpym)](PF(6)) revealed that the iridium center adopts a distorted octahedral geometry. All complexes exhibited intense and long-lived emission at room temperature. The substituents on the 2,2';-bipyridine moieties influence the photophysical and electrochemical properties. The excited states were investigated through theoretical calculations together with photophysical and electrochemical properties. It was found that the excited state of the [Ir(piq)(2)(FbpyF)](PF(6)) complex can be assigned to a mixed character of (3)LC (pi(N boolean AND N) -> pi*(N boolean AND N)), (3)MLCT, (3)LLCT (pi(C boolean AND N)->pi*(N boolean AND N)), and (3)LC (pi(C boolean AND N)->pi*(C boolean AND N)), In addition, the alkylfluorene-substituted complex, [Ir(piq)(2)(FbpyF)](PF(6)), had relatively high quantum efficiency and good film-forming ability, and it was expected to be a good candidate for lighting and display applications. A nondoped, single-layer device that incorporates this complex as a light-emitting layer was fabricated and red phosphorescence was obtained.

• 出版日期2008-5
• 单位南京邮电大学