Binding of ureas and amides to a Cu(II) terpyridine complex in methanol

作者：Dorazco Gonzalez Alejandro; Yatsimirsky Anatoly K^*

来源：Inorganica Chimica Acta, 2010, 363(1): 270-274.

DOI：10.1016/j.ica.2009.09.019

• Copper(II)
• Terpyridine
• Amides
• Ureas
• Binding
• Methanol solution

The binding of seven ureas and amides to Cu(terpy)(2+) in methanol has been studied by EPR, NMR and UV-Vis spectroscopy. The association constants range from 6.5 M (1) for acetamide to 45.3 M (1) for propyleneurea and correlate with the gas phase basicity of ligands. In methanol/water mixtures the affinity drops rapidly on increase in water content to 20 vol.%, but the binding of propyleneurea is detectable with K = 4.1 M (1) even in pure aqueous medium.

• 出版日期2010-1-4