A thermally robust amine-imine nickel catalyst precursor for living polymerization of ethylene above room temperature

作者：Gao, Haiyang^*; Hu, Haibin; Zhu, Fangming; Wu, Qing

来源：Chemical communications, 2012, 48(27): 3312-3314.

DOI：10.1039/c2cc17154f

A bulky amine-imine nickel complex containing two 2,6-diisopropyl substituents after activation with MMAO or Et2AlCl can polymerize ethylene in a living fashion over a period of 120 minutes at room temperature or above.

• 出版日期2012
• 单位中山大学