Ultrasound assisted co-precipitation of nanostructured CuO-ZnO-Al2O3 over HZSM-5: Effect of precursor and irradiation power on nanocatalyst properties and catalytic performance for direct syngas to DME

作者：Allahyari Somaiyeh; Haghighi Mohammad^*; Ebadi Amanollah; Hosseinzadeh Shahin

来源：Ultrasonics Sonochemistry, 2014, 21(2): 663-673.

DOI：10.1016/j.ultsonch.2013.09.014

• CuO-ZnO-Al2O3/HZSM-5
• Direct synthesis of DME
• Ultrasound assisted co-precipitation
• Irradiation power

Nanostructured CuO-ZnO-Al2O3/HZSM-5 was synthesized from nitrate and acetate precursors using ultrasound assisted co-precipitation method under different irradiation powers. The CuO-ZnO-Al2O3/HZSM-5 nanocatalysts were characterized using XRD, FESEM, BET, FTIR and EDX Dot-mapping analyses. The results indicated precursor type and irradiation power have significant influences on phase structure, morphology, surface area and functional groups. It was observed that the acetate formulated CuO-ZnO-Al2O3/HZSM-5 nanocatalyst have smaller CuO crystals with better dispersion and stronger interaction between components in comparison to nitrate based nanocatalysts. Ultrasound assisted co-precipitation synthesis method resulted in nanocatalyst with more uniform morphology compared to conventional method and increasing irradiation power yields smaller particles with better dispersion and higher surface area. Additionally the crystallinity of CuO is lower at high irradiation powers leading to stronger interaction between metal oxides. The nanocatalysts performance were tested at 200-300 degrees C, 10-40 bar and space velocity of 18,000-36,000 cm(3)/g h with the inlet gas composition of H-2/CO = 2/1 in a stainless steel autoclave reactor. The acetate based nanocatalysts irradiated with higher levels of power exhibited better reactivity in terms of CO conversion and DME yield. While there is an optimal temperature for CO conversion and DME yield in direct synthesis of DME, CO conversion and DME yield both increase with the pressure increase. Furthermore ultrasound assisted co-precipitation method yields more stable CuO-ZnO-Al2O3/HZSM-5 nanocatalyst while conventional precipitated nanocatalyst lost their activity ca. 18% and 58% in terms of CO conversion and DME yield respectively in 24 h time on stream test.

• 出版日期2014-3