Stepwise Vapochromism Observed for a Simple Terpyridine-Platinum(II) Complex with a Thiocyanato Ligand

作者：Kobayashi Atsushi; Fukuzawa Yuki; Noro Shin ichiro; Nakamura Takayoshi; Kato Masako^*

来源：Chemistry Letters, 2009, 38(10): 998-999.

DOI：10.1246/cl.2009.998

A simple Pt-II-terpyridine complex [Pt(NCS)(tpy)](SCN) (tpy = 2,2': 6', 2 ''-terpyridine) shows distinct two-step vapochromism from red to yellow through dark red in response to methanol vapor. The adsorption isotherm for methanol vapor reveals that the two-step vapochromic behavior originates from breathing-like structural transformations.

• 出版日期2009-10-5