Aqua[2-(3-carboxy-5-carboxylatophenoxy)acetato-kappa O-1]bis(1,10-phenanthroline-kappa N-2,N ')manganese(II) dihydrate

作者：Cai Yi Ni; Chen Jing; Feng Yun Long^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2010, 66: M1641-U1438.

DOI：10.1107/S1600536810048142

In the title complex, [Mn(C10H6O7)(C12H8N2)(2)(H2O)]center dot 2H(2)O, the Mn-II atom is coordinated by two O atoms from one 2-(3-carboxy-5-carboxylatophenoxy)acetate (HOABDC(2-)) dianion and one water molecule and by four N atoms from two 1,10-phenanthroline (phen) ligands within a distorted octahedral geometry. O-H center dot center dot center dot O hydrogen bonding between COOH and -COO- groups of adjacent molecules and between carboxylate groups and coordinated and uncoordinated water molecules leads to a three-dimensional structure which is further stabilized by weak pi-pi interactions of adjacent phen ligands with centroid-centroid separations of 4.2932 (1) angstrom.

• 出版日期2010-12
• 单位浙江师范大学