Aurophilicity under pressure: a combined crystallographic and in situ spectroscopic study

作者:O'Connor Alice E; Mirzadeh Nedaossadat*; Bhargava Suresh K; Easun Timothy L; Schroeder Martin; Blake Alexander J*
来源:Chemical Communications, 2016, 52(41): 6769-6772.
DOI:10.1039/c6cc00923a

摘要

High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}(2)] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

  • 出版日期2016