Double-layer structure, sorption and magnetism properties of metal-organic frameworks with trigonal planar ligand

作者：Zhang, Xiuling^*; Zhang, Yongzheng; Hu, Hui; Chen, Zhaohua; Yuan, Zaiwu

来源：Inorganic Chemistry Communications, 2015, 55: 65-68.

DOI：10.1016/j.inoche.2015.03.015

• Trigonal planar ligand
• Metal-organic framework
• Gas adsorption
• Magnetic studies

A new double-layer metal-organic framework [Co-3(tcpt)(2)(H2O)(2)] (1) has been synthesized using trigonal planar ligand 2,4,6-tris(4-carboxyphenoxy)-1,3,5-triazine (H(3)tcpt) as a bridging ligand and characterized by single-crystal X-ray diffraction, elemental analyses, IR, PXRD and TGA. Structure analysis reveals that compound 1 has a double-layer structure. Gas sorption measurements indicate that compound 1 exhibits selective adsorption capabilities for CO2 over CH4 and N-2. Furthermore, the magnetic studies of compound 1 show antiferromagnetic interactions between Co(II) ions.

• 出版日期2015-5
• 单位山东大学; 德州学院