A 3D Keggin-based framework containing Ag-I-ribbons and cycles by using rigid tetrazole-based ligand

作者：Tian Aixiang^*; Lin Xiaoling; Sun Na; Ying Jun; Zhang Juwen; Li Na; Wang Xiuli

来源：Inorganic Chemistry Communications, 2014, 40: 51-54.

DOI：10.1016/j.inoche.2013.11.032

• Keggin polyoxometalate
• Hydrothermal synthesis
• Rigid ptz ligand
• Electrochemical property

A new Keggin-type polyoxometalate (POM)-based compound, [Ag-9(ptz)5][(PMo11MoVO40)-Mo-VI]center dot H2O (1) (ptzH = 5-phenyl-1H-tetrazole), was synthesized under hydrothermal conditions. Compound 1 exhibits a 2D layer containing Ag-I ribbons and hexa-nuclear Ag-I circles, which are further linked by Ag-I atoms and [(PMo11MoO40)-Mo-VI-O-V](4-) anions to construct a 3D framework. The electrochemical properties of compound 1 have been investigated.

• 出版日期2014-2
• 单位渤海大学; 河北化工医药职业技术学院