Zwitterionic diaminodicyanoquinodimethanes with enhanced blue-green emission in the solid state

作者：Chandaluri Ch G; Radhakrishnan T P^*

来源：Optical Materials, 2011, 34(1): 119-125.

DOI：10.1016/j.optmat.2011.07.033

• Diaminodicyanoquinodimethane
• Crystal structure
• Fluorescence
• Blue emission
• Semiempirical calculations

Diaminodicyanoquinodimethane molecules which show strong solid state emission in the blue-green region are developed. The new materials are structurally characterized; extended supramolecular assemblies mediated by H-bond interactions are observed in the crystal lattice. Spectroscopic studies including life-time and fluorescence quantum yield measurements in the solution and solid states are carried out. Emission in the solid state is similar to 400 times stronger than that in solution; this can be attributed to the inhibition of the excited state geometry relaxation to a non-radiative state, in the solid. Impact of the molecular structure in the crystals on the solid state light emission is discussed. Semiempirical computational studies provide useful insight into the various structural and spectroscopic features of the new materials. The present observations serve as a pointer to further design strategies for realizing novel blue photoluminescent molecular materials based on the diaminodicyanoquinodimethane framework.

• 出版日期2011-11