Ultrahigh adsorption of typical antibiotics onto novel hierarchical porous carbons derived from renewable lignin via halloysite nanotubes-template and in-situ activation

作者：Xie, Atian; Dai, Jiangdong^*; Chen, Xiang; Ma, Ping; He, Jinsong; Li, Chunxiang; Zhou, Zhiping; Yan, Yongsheng^*

来源：Chemical Engineering Journal, 2016, 304: 609-620.

DOI：10.1016/j.cej.2016.06.138

• Ultrahigh-performance antibiotics removal
• Renewable SLS
• Hierarchical porous carbons
• In-situ KOH activation
• Halloysite nanotubes template

In decade years, antibiotics residual has received considerable attention because of their detrimental effects on human health and the ecosystem, thereby resolution of this issue become a burning research project. Herein, we first prepared a novel sustainable hierarchical porous carbons (HPCs) (named LCTA) via the combination of halloysite nanotubes-template and in-situ KOH activation, using industrial by-product sodium lignin sulfonate (SLS) as biomass precursor. It was demonstrated that both HNTs template and KOH activation played a key role in the enhancements of the porosity and accessible surface. LTCA exhibited a high specific surface area of 2320 m(2)/g and large pore volume of 1.342 cm(3)/g. Moreover, LTCA showed an ultrahigh adsorption capacity for tetracycline (TC) of 1297.0 mg/g and chloramphenicol (CAP) of 1067.2 mg/g at 298 K, which are far higher than those adsorbents previously reported. Additionally, fast adsorption kinetics, excellent environmental adaptability and good regeneration ability make this novel HPC as a promising material for antibiotics wastewater treatment practices.

• 出版日期2016-11-15
• 单位江苏大学