摘要

This review summarizes recent advances conducted by our group on related silver complexes of (a) all-carbon ligands C-6(2-) and C-8(2-), (b) 1, 5-hexadiyne-1, 6-diide C6H42-, (c) ethynediide C-2(2-) and ethynide R-C-2(-) assembled with phosphonic acids, (d) aryl, alicyclic and heteroaromatic ethynides, and (e) ethynides that are stabilized by different types of silver center dot center dot center dot carbon binding interactions in the crystalline state, which are further consolidated by weak intra/intermolecular forces. The effects of the solvent, bulkiness of ligands and ancillary ligands on the construction of coordination networks are also discussed.