A Flexible Route toward Polypropylene Model Compounds of Various Tacticities

作者：Drooghaag Xavier^*; Henry Gaetan; Marchand Brynaert Jacqueline

来源：Synthesis, 2010, (21): 3755-3760.

DOI：10.1055/s-0030-1258233

• model hydrocarbons
• polyolefins
• total synthesis
• HPLC
• NMR

This paper reports the flexible synthesis of 2,4,6,8,10-pentamethylundecane (PMU) as well as a chromatographic method for the separation of its diastereoisomers. This strategy offers a unique opportunity to accede to three model compounds of polypropylene (PP) of different tacticities (i.e., isotactic, syndiotactic, and atactic PP).

• 出版日期2010-11