Aqua(1,10-phenanthroline-kappa N-2,N ')(DL-threoninato-kappa 2N,O-1)copper(II) chloride dihydrate

作者：Tan Yi Han; Teoh Siang Guan; Sek Kei Lin; Loh Wan Sin; Fun Hoong Kun^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2010, 66: M595-U1148.

DOI：10.1107/S1600536810015278

The asymmetric unit of the title compound, [Cu(C4H8NO3)(C12H8N2)(H2O)]Cl center dot 2H(2)O, contains a complex cation, a chloride anion and two water molecules. The Cu-II ion has a distorted square-pyramidal coordination geometry formed by one bidentate phenanthroline ligand, one O, N-bidentate dlthreoninate ligand and one apical water molecule. In the crystal structure, intermolecular O-H center dot center dot center dot O, N-H center dot center dot center dot O, NH center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds link the components into layers. A single weak intermolecular C-H center dot center dot center dot O interaction connects these layers into a three-dimensional network.

• 出版日期2010-5