Accessible heavier s-block dihydropyridines: structural elucidation and reactivity of isolable molecular hydride sources

作者：Orr Samantha A; Kennedy Alan R; Liggat John J; McLellan Ross; Mulvey Robert E; Robertson Stuart D

来源：Dalton Transactions, 2016, 45(14): 6234-6240.

DOI：10.1039/c5dt04224k

Transmetallation of lithiodihydropyridines with Group 1 alkoxides provides facile access to reactive MH (M = Na, K) sources, which show significant structural diversity due in part to the distinct ways that Na/K engage with the σ (green) and π (red) donor systems of the DHP ligands.

• 出版日期2016
• 单位university of strathclyde