A stable open-shell redox active ditopic ligand

作者:Bonanno N M; Lough A J; Prosser K E; Wal**y C J; Poddutoori P K; Lemaire M T*
来源:Dalton Transactions, 2016, 45(13): 5460-5463.
DOI:10.1039/c5dt04061b

摘要

Herein we describe the synthesis, structure and electronic properties of an unusual redox-active ditopic ligand with a stable open-shell configuration. This stable phenoxyl radical features intense and very low energy electronic transitions in the near infrared (NIR) part of the spectrum and is structurally set up to strongly spin couple coordinated transition metal ions in [2 x 2] grid-type structures.

  • 出版日期2016