科研之友
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摘要
A novel complex, {[Cd(1,3-bdc)(bte)(0.5)(H2O)]center dot H2O}(n) (1) (1,3-bdc = 1,3-benzenedicarboxyl-ate and bte = bis(triazol)ethane), has been hydrothermally synthesized and structurally characterized. Single-crystal x-ray diffraction analysis reveals that complex 1 features a (3,4)-connected two-dimensional (2D) binodal net with the point symbol of (4(2).6) (4(2).6(3).8) in terms of the rationalization of 1,3-bdc and Cd-II as 3- and 4-connected nodes, respectively. Additionally, these 2D networks of 1 are extended by pi-pi stacking and cyclic R-6(6)(16) H-bonding into three-dimensional (3D) architecture. Solid-state properties, such as photoluminescence and thermal stability of 1, have also been studied.
