A C-3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties

作者：Segarra Candela; Linke Jens; Mas Marza Elena; Kuck Dietmar^*; Peris Eduardo

来源：Chemical Communications, 2013, 49(90): 10572-10574.

DOI：10.1039/c3cc46155f

A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C-3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the three metals are essentially disconnected.

• 出版日期2013