Numerical analysis of impurity separation from waste salt by investigating the change of concentration at the interface during zone refining process

作者：Choi Ho Gil; Shim Moonsoo; Lee Jong Hyeon; Yi Kyung Woo^*

来源：Journal of Crystal Growth, 2017, 474: 69-75.

DOI：10.1016/j.jcrysgro.2016.12.083

• Lithium chloride
• Zone refining
• 3-D simulation
• Decontamination factor

The waste salt treatment process is required for the reuse of purified salts, and for the disposal of the fission products contained in waste salt during pyroprocessing. As an alternative to existing fission product separation methods, the horizontal zone refining process is used in this study for the purification of waste salt. In order to evaluate the purification ability of the process, three-dimensional simulation is conducted, considering heat transfer, melt flow, and mass transfer. Impurity distributions and decontamination factors are calculated as a function of the heater traverse rate, by applying a subroutine and the equilibrium segregation coefficient derived from the effective segregation coefficients. For multipass cases, 1d solutions and the effective segregation coefficient obtained from three-dimensional simulation are used. In the present study, the topic is not dealing with crystal growth, but the numerical technique used is nearly the same since the zone refining technique was just introduced in the treatment of waste salt from nuclear power industry because of its merit of simplicity and refining ability. So this study can show a new application of single crystal growth techniques to other fields, by taking advantage of the zone refining multipass possibility. The final goal is to achieve the same high degree of decontamination in the waste salt as in zone freezing ( or reverse Bridgman) method.

• 出版日期2017-9-15