A thermally reversible photoinduced magnetic trinuclear complex [Cu-2(bpmen)(2)][Mo-IV(CN)(8)]center dot 8H(2)O

作者：Xu, Haitao^*; Sato, Osamu; Li, Zhihua; Ma, Jianping

来源：Inorganic Chemistry Communications, 2012, 15: 311-313.

DOI：10.1016/j.inoche.2011.11.013

• Crystal structure
• Trinuclear complex
• Molecule-based materials
• Photomagnetic property
• Charge transfer

A trinuclear complex [Cu-2(II)(bpmen)(2)][Mo-IV(CN)(8)]center dot 8H(2)O was synthesized and structurally characterized, crystallized in the monoclinic system, space group Cc with cell constants a = 11.726(2) angstrom, b = 17.158(3) angstrom, c = 23.891(5) angstrom, beta = 97.96(3)degrees and Z = 4. It exhibited thermally reversible photo-responsive properties on UV light irradiation through a Mo-IV to Cu-II charge transfer, which is potential interest for the molecular storage of information as a multifunctional molecule-based material.

• 出版日期2012-1
• 单位山东师范大学; 华东理工大学